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Hanna Instruments Australia
Sales: (03) 9769 0666   |    Mon to Fri: 8:30am – 5:00pm

How to Clean a pH Meter Probe

Maintaining the accuracy and longevity of your pH meter probe is crucial for obtaining reliable measurements. Regular cleaning of the probe is essential as it can be contaminated by residues from the solutions it measures. Here is a comprehensive guide on how to properly clean a pH meter probe.

Why Cleaning is Important
The pH meter probe, often called the electrode, is the most sensitive part of the pH meter. It can accumulate residues from the sample solutions, which can affect its accuracy and response time. Regular cleaning ensures that the electrode provides consistent and accurate readings, prolonging the life of the probe. Here are some steps you can take to keep your electrode clean.

Materials Needed

  • Distilled or deionized water
  • pH electrode cleaning solution
  • Beaker or container
  • Application-specific cleaning solution (if needed)
  • Mild detergent (optional)
  • Storage solution (optional)

Step-by-Step Cleaning Procedure

1. Rinse with Distilled Water: Start by rinsing the probe with distilled or deionized water to remove any loose particles. Hold the probe under a gentle stream of water or immerse it in a container filled with distilled water.

2. Soak in Cleaning Solution: Soak the electrode in a general cleaning solution or an appropriate use-specific cleaning solution for at least 15 minutes to dissolve contamination. Whenever possible, use a cleaning solution specifically designed for your application, as these are formulated to effectively remove the specific types of stains and deposits from your samples. For example, a cleaning solution for winemaking will effectively remove the deep stains left by red wine and must. Avoid using harsh chemicals or abrasive materials, as they can damage the sensitive glass membrane of the probe.

  • Application specific cleaning:
    1. Protein Coating:
    2. Inorganic Soak:
      • Soak the electrode in HI7074L Inorganic Cleaning Solution for at least 15 minutes to remove precipitates caused by reactions with silver in the filling solution.
      • Rinse the electrode with water.
      • Allow it to rehydrate in HI70300L storage solution for at least one hour (overnight for best results).
    3. Oil and Grease:
      • Soak the electrode in HI7077L Oil and Fat Cleaning Solution for at least 15 minutes to remove oil and grease residues without damaging the electrode.
      • Rinse the electrode with water.
      • Allow it to rehydrate in HI70300L storage solution for at least one hour (overnight for best results).


3. Rinse Thoroughly:
After cleaning, rinse the pH electrode thoroughly with distilled or deionized (DI) water. Then, soak the electrode in a storage solution for at least 2-3 hours before calibration. For optimal results, we recommend soaking the electrode overnight. This step is crucial to prevent any residual cleaning agent from affecting future measurements.

4. Store the Probe: If you need to store the probe, ensure it is adequately moist according to the manufacturer’s recommendations, usually in a storage solution or buffer. Keep the electrode in a protective cap filled with storage solution. If your probe does not have a cap, use a small container that can hold the probe and enough storage solution to cover the glass bulb. After long-term storage, soak the electrode in storage solution for at least 2-3 hours before use. For best results, soak it overnight to ensure the glass membrane is fully hydrated.

5. Calibration: After cleaning, it’s essential to calibrate the pH meter to ensure accurate readings. Our calibration buffers are designed to have a long shelf life when left unopened. Once opened, a buffer with a pH lower than 7 will last around 4-8 weeks, while a buffer with a pH over 7 will be good for about 1-2 weeks. To prevent contamination of your calibration solutions, never submerge your electrode right into the bottle. Pour out just what is needed into a container that has been rinsed with DI water and use that for your calibration. Never pour used buffer back into the bottle! Read our article about how to calibrate your pH electrode.

Maintaining a clean pH meter probe is essential for accurate and reliable measurements. By following these cleaning and maintenance steps, you can ensure the optimal performance of your pH meter.

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